Solid–liquid equilibria for the dimethyl ether + carbon dioxide binary system

Group Contribution Method for Predicting the Phase Behavior of Binary Mixtures Containing Carbon Dioxide

Binary Vapor-liquid Equilibria of Carbon Dioxide-light Hydrocarbons at Low Temperature*

light hydrocarbons at low temperatures is of interest in the design of the proper equipment to make such separations. In the previous paper4) of this series, the equilibrium relationships for two binary mixtures of carbon dioxide with ethylene and ethane at 0°C have been described. Those for the ethylene and ethsine binaries with carbon dioxide have been shown to form, minimum-boiling azeotrope...

Molecular model for carbon dioxide optimized to vapor-liquid equilibria.

A molecular model for carbon dioxide is presented, and the parameters of the Lennard-Jones sites, the bond length, and the quadrupole moment are optimized to experimental vapor-liquid equilibrium data. The resulting molecular model shows mean unsigned deviations to the experiment over the whole temperature range from triple point to critical point of 0.4% in saturated liquid density, 1.8% in va...

Hollow alumina nanospheres as novel catalyst for the conversion of methanol to dimethyl ether

This paper investigates hollow and porous alumina nanospheres that were previously synthesized to be used for the dehydration of methanol to dimethyl ether (DME). As hollow nanostructures possess characteristics such as low density and high surface to volume ratio, their catalytic activity between hollow and porous structure is compared. For this purpose, three most important parameters (acidit...

Correlative biosorption equilibria model for a binary batch system

The binary sorption of copper and nickel ions onto peat has been studied. Equilibrium isotherms have been determined for three di!erent copper : nickel molar concentration ratios. The experimental results have been analysed using an extended multicomponent Langmuir equation with a competition term but the correlation between the experimental and the predicted values was poor. An interaction fac...